#\#CIF_1.1

#  CIF produced by WinGX routine CIF_UPDATE
#  Created on 2022-08-03 at 16:29:51
#  Using CIFtbx version 3.0.4  1 Sep 2006

#  Dictionary name : cif_core.dic
#  Dictionary vers : 2.4.5
#  Request file    : c:\program files (x86)\wingx\files\archive.reqdat
#  CIF files read  : shelx project

#------------------ SECTION 1. GLOBAL INFORMATION ---------------------------#

data_global

#------------------ AUDIT DETAILS -------------------------------------------#

_audit_creation_date            2022-08-03
_audit_creation_method          'WinGX routine CIF_UPDATE'
_audit_conform_dict_name        cif_core.dic
_audit_conform_dict_version     2.4.3
_audit_conform_dict_location    ftp://ftp.iucr.org/pub/cif_core.dic
_audit_update_record            ?

#------------------ AUTHOR DETAILS -------------------------------------------#

# Name and address of author for correspondence

_publ_contact_author_name       ' ,  '
_publ_contact_author_address
;

;
_publ_contact_author_email       ' '
_publ_contact_author_fax         ' '
_publ_contact_author_phone       ' '


# Insert blank lines between references

_publ_section_references
;
Blessing, R. H. (1995) Acta Cryst., A51, 33-38.

Blessing, R. H. (1987) Cryst. Rev. 1, 3-58.

Blessing, R. H. (1989) J. Appl. Cryst. 22, 396-397.

Bruker (2012) APEX2 (Version 2012.10-0), SAINT (version 8.27B), SADABS
(version 2012/1), BrukerAXS Inc, Madison, Wisconsin, USA.

ABSCOR: Higashi, T. (1995). ABSCOR. Rigaku Corporation, Tokyo, Japan.

CAD-4 Software: Enraf-Nonius (1989). CAD-4 Software (or CAD-4 EXPRESS).
Enraf-Nonius, Delft, The Netherlands.

Cambridge Structural Database: Allen, F. R. (2002). Acta Cryst. B58, 380-388.

CAMERON: Watkin, D. J., Prout, C. K. & Pearce, L. J. (1996). CAMERON.
Chemical Crystallography Laboratory, Oxford, England.

CrysAlis CCD, CrysAlis RED and associated programs: Oxford Diffraction (2006).
Program name(s). Oxford Diffraction Ltd, Abingdon, England.

CRYSTALS: Betteridge, P. W., Carruthers, J. R., Cooper, R. I., Prout, K. &
Watkin, D. J. (2003). J. Appl. Cryst. 36, 1487.

COLLECT: Nonius (1998). COLLECT. Nonius BV, Delft, The Netherlands.

DENZO/SCALEPACK:  Otwinowski, Z. & Minor, W. (1997). Methods in Enzymology,
Vol. 276, Macromolecular Crystallography, Part A, edited by C. W. Carter Jr
& R. M. Sweet, pp. 307-326. New York: Academic Press.

DIAMOND: Brandenburg, K.(2006). DIAMOND. Crystal Impact GbR, Bonn, Germany.

DIF4 and REDU4: Stoe & Cie (1991). Program name(s). Stoe & Cie, Darmstadt,
Germany.

DIFABS: Walker, N. &  Stuart, D. (1983). Acta Cryst., A39, 158 - 166.

DIRAX: Duisenberg, A. J. M. (1992). J. Appl. Cryst. 25, 92-96.

DIRDIF-2008: Beurskens, P.T., Beurskens, G., de Gelder, R., Garciía-Granda,
S., Gould, R.O. & Smits, J.M.M. (2008) The DIRDIF-2008 program
system, Crystallography Laboratory, Radboud University  Nijmegen,
The Netherlands.

EDMA: Palatinus, L., Prathapa, S. J. & van Smaalen, S. (2012) J. Appl. Cryst.
45, 575-580.

enCIFer: Allen, F. H., Johnson, O., Shields, G. P., Smith, B. R. & Towler,
M. (2004). J. Appl. Cryst. 37, 335-338.

EVALCCD: Duisenberg, A. J. M., Kroon-Batenburg, L. M. J. & Schreurs,
A. M. M. (2003). J. Appl. Cryst. 36, 220-229.

JANA2000: Petricek, V. & Dusek, M. (2000). JANA2000. Institute of Physics,
Czech Academy of Sciences, Prague, Czech Republic.

MERCURY: Macrae, C. F., Bruno, I. J., Chisholm, J. A., Edgington,
P. R., McCabe, P., Pidcock, E., Rodriguez-Monge, L., Taylor, R.,
van de Streek, J. & Wood, P. A. (2008). J. Appl. Cryst. 41, 466-470.

MOGUL: Bruno, I. J., Cole, J. C., Kessler, M., Luo, J., Motherwell,
W. D. S., Purkis, L. H., Smith, B. R., Taylor, R., Cooper, R. I., Harris,
S. E. & Orpen, A. G. (2004). J. Chem. Inf. Comput. Sci. 44, 2133-2144.

ORTEPII: Johnson, C. K. (1976). ORTEPII. Report ORNL-5138. Oak Ridge
National Laboratory, Tennessee, USA.

ORTEPIII:  Burnett, M. N. & Johnson, C. K. (1996). ORTEPIII.
Report ORNL-6895. Oak Ridge National Laboratory, Tennessee, USA.

ORTEP-3: Farrugia, L. J. (2012). J. Appl. Cryst. 45, 849-854.

PARST: Nardelli, M. (1995). J. Appl. Cryst. 28, 659.

PLATON: Spek, A. L. (2009). Acta. Cryst. D65, 148-155.

PROCESS: Rigaku (1996). PROCESS. Rigaku Corporation, Tokyo, Japan.

PROCESS-AUTO: Rigaku (1998). PROCESS-AUTO. Rigaku Corporation, Tokyo, Japan.

PublCIF: Westrip, S. P. (2010). J. Appl. Cryst. 43, 920-925.

SCHAKAL: Keller, E. (1999) University of Freiburg, Germany.

SHELX: Sheldrick, G. M. (2015). Acta Cryst. C71, 3-8.

SHELXD: Schneider, T. R. & Sheldrick, G. M. (2002) Acta Cryst. D58, 1772-1779.

SHELXT: Sheldrick, G. M. (2015). Acta Cryst. A71, 3-8.

SIR92: Altomare, A., Cascarano, G., Giacovazzo, C., Guagliardi, A., Burla,
M. C., Polidori, G. & Camalli, M. (1994). J. Appl. Cryst. 27, 435.

SIR97: Altomare, A., Burla, M. C., Camalli, M., Cascarano, G. L.,
Giacovazzo, C., Guagliardi, A., Moliterni, A. G. G., Polidori, G. &
Spagna, R. (1999). J. Appl. Cryst. 32, 115-119.

SIR2002: Burla, M. C., Camalli, M., Carrozzini, B., Cascarano, G. L.,
Giacovazzo, C., Polidori, G. & Spagna, R. (2003). J. Appl. Cryst. 36, 1103.

SIR2004: Burla, M. C., Caliandro, R., Camalli, M., Carrozzini, B.,
Cascarano, G. L., De Caro, L., Giacovazzo, C., Polidori, G. & Spagna, R.
(2005). J. Appl. Cryst. 38, 381-388.

SIR2008 & IL MILIONE: Burla, M. C., Caliandro, R., Camalli, M., Carrozzini, B.,
Cascarano, G. L., De Caro, L., Giacovazzo, C., Polidori, G., Siliqi, D.,
& Spagna, R. (2007). J. Appl. Cryst. 40, 609-613.

SIR2011: Burla, M. C., Caliandro, R., Camalli, M., Carrozzini, B.,
Cascarano, G. L., Giacovazzo, C., Mallamo, M., Mazzone, A., Polidori, G.
& Spagna, R. (2012). J. Appl. Cryst. 45, 357-361.

SUPERFLIP: Palatinus, L. & Chapuis, G. (2007) J. Appl. Cryst. 40, 786-790.

TEXSAN: Molecular Structure Corporation & Rigaku (2000). TEXSAN. MSC,
The Woodlands, Texas, USA, and Rigaku Corporation, Tokyo, Japan.

WinGX: Farrugia, L. J. (2012). J. Appl. Cryst. 45, 849-854.

X-AREA, X-RED, X-RED32, X-SHAPE:  Stoe & Cie (2002). Program name(s).
Stoe & Cie GmbH, Darmstadt, Germany.

XCAD4: Harms, K. & Wocadlo, S. (1995). XCAD4. University of Marburg, Germany.

XSCANS: Siemens (1994). XSCANS. Siemens Analytical X-ray Instruments Inc.,
Madison, Wisconsin, USA.

;

#------------------  SECTION 2. COMPOUND(S) DETAILS -------------------------#

data_shelx

_audit_creation_date                    2022-08-03T16:29:51-00:00
_audit_creation_method                  'WinGX routine CIF_UPDATE'
_audit_conform_dict_name                cif_core.dic
_audit_conform_dict_version             2.4.5
_audit_conform_dict_location            ftp://ftp.iucr.org/pub/cif_core.dic
_publ_requested_category                FI

#----------------------------------------------------------------------------#
#                   CHEMICAL INFORMATION                                     #
#----------------------------------------------------------------------------#

_chemical_formula_sum                   'Cl5 Co Rb3'
_chemical_formula_weight                492.59

#----------------------------------------------------------------------------#
#                   UNIT CELL INFORMATION                                    #
#----------------------------------------------------------------------------#

_symmetry_cell_setting                  tetragonal
_symmetry_space_group_name_H-M          'I 4/m c m'
_symmetry_space_group_name_Hall         '-I 4 2c'
_symmetry_Int_Tables_number             140
loop_
    _symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z'
'-y, x, z'
'y, -x, z'
'-x, y, -z+1/2'
'x, -y, -z+1/2'
'y, x, -z+1/2'
'-y, -x, -z+1/2'
'x+1/2, y+1/2, z+1/2'
'-x+1/2, -y+1/2, z+1/2'
'-y+1/2, x+1/2, z+1/2'
'y+1/2, -x+1/2, z+1/2'
'-x+1/2, y+1/2, -z+1'
'x+1/2, -y+1/2, -z+1'
'y+1/2, x+1/2, -z+1'
'-y+1/2, -x+1/2, -z+1'
'-x, -y, -z'
'x, y, -z'
'y, -x, -z'
'-y, x, -z'
'x, -y, z-1/2'
'-x, y, z-1/2'
'-y, -x, z-1/2'
'y, x, z-1/2'
'-x+1/2, -y+1/2, -z+1/2'
'x+1/2, y+1/2, -z+1/2'
'y+1/2, -x+1/2, -z+1/2'
'-y+1/2, x+1/2, -z+1/2'
'x+1/2, -y+1/2, z'
'-x+1/2, y+1/2, z'
'-y+1/2, -x+1/2, z'
'y+1/2, x+1/2, z'

_cell_length_a                          8.6958(2)
_cell_length_b                          8.6958(2)
_cell_length_c                          14.1842(4)
_cell_angle_alpha                       90
_cell_angle_beta                        90
_cell_angle_gamma                       90
_cell_volume                            1072.57(6)
_cell_formula_units_Z                   4
_cell_measurement_temperature           293(2)
_cell_measurement_reflns_used           16521
_cell_measurement_theta_min             2.91
_cell_measurement_theta_max             27.48
_cell_measurement_wavelength            0.71073

#----------------------------------------------------------------------------#
#                   CRYSTAL INFORMATION                                      #
#----------------------------------------------------------------------------#

_exptl_crystal_size_max                 0.13
_exptl_crystal_size_mid                 0.12
_exptl_crystal_size_min                 0.106
_exptl_crystal_density_diffrn           3.05
_exptl_crystal_density_method           'not measured'
_exptl_crystal_F_000                    892
loop_
    _exptl_crystal_face_index_h
    _exptl_crystal_face_index_k
    _exptl_crystal_face_index_l
    _exptl_crystal_face_perp_dist
-1 0 0 0.053
1 0 0 0.053
0 0 -1 0.065
0 0 1 0.065
0 1 0 0.06
0 -1 0 0.06
0 1 -2 0.049
0 1 1 0.054
1 0 -2 0.06
1 0 2 0.06


#----------------------------------------------------------------------------#
#                   ABSORPTION CORRECTION                                    #
#----------------------------------------------------------------------------#

_exptl_absorpt_coefficient_mu           16.297
_exptl_absorpt_correction_type          multi-scan
_exptl_absorpt_process_details
;
        [c.f. r.h. blessing, acta cryst. (1995), a51, 33-38]
;
_exptl_absorpt_correction_T_min         0.0751
_exptl_absorpt_correction_T_max         0.1353
_shelx_estimated_absorpt_T_min          0.226
_shelx_estimated_absorpt_T_max          0.277

#----------------------------------------------------------------------------#
#                   DATA COLLECTION                                          #
#----------------------------------------------------------------------------#

_diffrn_source                          'Enraf Nonius FR590'
_diffrn_ambient_temperature             293(2)
_diffrn_radiation_wavelength            0.71073
_diffrn_radiation_type                  MoK\a
_diffrn_radiation_monochromator         'horizonally mounted graphite crystal'
_diffrn_radiation_probe                 x-ray
_diffrn_detector                        'CCD plate'
_diffrn_detector_area_resol_mean        9
_diffrn_orient_matrix_ub_11             -0.000985
_diffrn_orient_matrix_ub_12             0.028104
_diffrn_orient_matrix_ub_13             0.068361
_diffrn_orient_matrix_ub_21             -0.114993
_diffrn_orient_matrix_ub_22             0.000068
_diffrn_orient_matrix_ub_23             -0.000633
_diffrn_orient_matrix_ub_31             -0.000319
_diffrn_orient_matrix_ub_32             -0.111511
_diffrn_orient_matrix_ub_33             0.017228
_diffrn_measurement_device              '95mm CCD camera on κ-goniostat'
_diffrn_measurement_device_type         KappaCCD
_diffrn_measurement_method              'CCD rotation images, thick slices'
_diffrn_standards_number                0
_diffrn_standards_interval_time         .
_diffrn_standards_interval_count        .
_diffrn_standards_decay_%               ?
_diffrn_reflns_av_R_equivalents         0.138
_diffrn_reflns_av_unetI/netI            0.0445
_diffrn_reflns_number                   5959
_diffrn_reflns_limit_h_min              -11
_diffrn_reflns_limit_h_max              11
_diffrn_reflns_limit_k_min              -11
_diffrn_reflns_limit_k_max              11
_diffrn_reflns_limit_l_min              -18
_diffrn_reflns_limit_l_max              18
_diffrn_reflns_theta_min                3.313
_diffrn_reflns_theta_max                27.49
_diffrn_reflns_theta_full               25.242
_diffrn_measured_fraction_theta_full
                                        0.996
_diffrn_measured_fraction_theta_max
                                        0.997
_diffrn_reflns_Laue_measured_fraction_full
                                        0.996
_diffrn_reflns_Laue_measured_fraction_max
                                        0.997
_diffrn_reflns_point_group_measured_fraction_full
                                        0.996
_diffrn_reflns_point_group_measured_fraction_max
                                        0.997
_reflns_Friedel_coverage                0
_reflns_number_total                    352
_reflns_number_gt                       341
_reflns_threshold_expression            'I > 2σ(I)'

#----------------------------------------------------------------------------#
#                   COMPUTER PROGRAMS USED                                   #
#----------------------------------------------------------------------------#

_computing_data_collection              'Collect (Bruker AXS BV, 1997-2004)'
_computing_cell_refinement
                                       'HKL Scalepack (Otwinowski & Minor 1997)'
_computing_data_reduction
                             'HKL Denzo and Scalepack (Otwinowski & Minor 1997)'
_computing_structure_refinement         'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics           'Ortep for Windows (Farrugia, 2012)'
_computing_publication_material
                                   'WinGX publication routines (Farrugia, 2012)'

#----------------------------------------------------------------------------#
#                   STRUCTURE SOLUTION                                       #
#----------------------------------------------------------------------------#


#----------------------------------------------------------------------------#
#                   REFINEMENT INFORMATION                                   #
#----------------------------------------------------------------------------#

_shelx_SHELXL_version_number            2018/3
_refine_ls_structure_factor_coef        Fsqd
_refine_ls_matrix_type                  full
_refine_ls_weighting_scheme             calc
_refine_ls_weighting_details
              'w=1/[σ²(Fo²)+(0.0117P)²+2.8625P] where P=(Fo²+2Fc²)/3'
_refine_ls_hydrogen_treatment           undef
_refine_ls_extinction_method            none
_refine_ls_number_reflns                352
_refine_ls_number_parameters            17
_refine_ls_number_restraints            0
_refine_ls_number_constraints           0
_refine_ls_R_factor_all                 0.0261
_refine_ls_R_factor_gt                  0.0255
_refine_ls_wR_factor_ref                0.0537
_refine_ls_wR_factor_gt                 0.0533
_refine_ls_goodness_of_fit_ref          1.167
_refine_ls_restrained_S_all             1.167
_refine_ls_shift/su_max                 0
_refine_ls_shift/su_mean                0
_refine_diff_density_max                0.661
_refine_diff_density_min                -1.33
_refine_diff_density_rms                0.185

#----------------------------------------------------------------------------#
#                   CONSTRAINTS AND RESTRAINTS                               #
#----------------------------------------------------------------------------#


#----------------------------------------------------------------------------#
#                   ATOMIC TYPES, COORDINATES AND THERMAL PARAMETERS         #
#----------------------------------------------------------------------------#

loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rb Rb -0.9393 2.9676 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

loop_
    _atom_site_label
    _atom_site_type_symbol
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_occupancy
    _atom_site_site_symmetry_order
    _atom_site_calc_flag
    _atom_site_refinement_flags_posn
    _atom_site_refinement_flags_adp
    _atom_site_refinement_flags_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
Rb1 Rb 0.16195(3) 0.66195(3) 0.5 0.01589(17) Uani 1 4 d S T P . .
Rb2 Rb 0.5 0.5 0.75 0.0220(2) Uani 1 8 d S T P . .
Co1 Co 0.5 1 0.75 0.0148(2) Uani 1 8 d S T P . .
Cl1 Cl 0.5 0.5 0.5 0.0202(4) Uani 1 8 d S T P . .
Cl2 Cl 0.35449(7) 0.85449(7) 0.65274(7) 0.0211(2) Uani 1 2 d S T P . .



#----------------------------------------------------------------------------#
#                   MOLECULAR GEOMETRY                                       #
#----------------------------------------------------------------------------#

_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_distance
    _geom_bond_site_symmetry_2
    _geom_bond_publ_flag
Rb1 Cl2 3.2094(9) 18_556 ?
Rb1 Cl2 3.2094(9) . ?
Rb1 Cl1 3.25953(16) 13 ?
Rb1 Cl1 3.25953(16) . ?
Rb1 Cl2 3.4442(8) 20_656 ?
Rb1 Cl2 3.4442(8) 19_466 ?
Rb1 Cl2 3.4442(8) 4_465 ?
Rb1 Cl2 3.4442(8) 3_655 ?
Rb1 Rb1 3.9832(9) 17_566 ?
Rb1 Co1 4.0671(2) 9_444 ?
Rb1 Co1 4.0671(2) 25_566 ?
Rb1 Rb1 4.6097(2) 3_665 ?
Rb2 Cl1 3.54605(11) 5_656 ?
Rb2 Cl1 3.54605(9) . ?
Rb2 Cl2 3.6065(5) . ?
Rb2 Cl2 3.6065(5) 28_656 ?
Rb2 Cl2 3.6065(5) 3_655 ?
Rb2 Cl2 3.6065(5) 26_546 ?
Rb2 Cl2 3.6065(5) 2_665 ?
Rb2 Cl2 3.6065(5) 4_565 ?
Rb2 Cl2 3.6065(5) 27_456 ?
Rb2 Cl2 3.6065(5) 25_566 ?
Co1 Cl2 2.2594(9) . ?
Co1 Cl2 2.2595(9) 28_656 ?
Co1 Cl2 2.2595(9) 27_466 ?
Co1 Cl2 2.2595(9) 2_675 ?

loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle_publ_flag
Cl2 Rb1 Cl2 84.92(4) 18_556 . ?
Cl2 Rb1 Cl1 75.813(7) 18_556 13 ?
Cl2 Rb1 Cl1 75.813(8) . 13 ?
Cl2 Rb1 Cl1 75.813(7) 18_556 . ?
Cl2 Rb1 Cl1 75.813(8) . . ?
Cl1 Rb1 Cl1 141.196(14) 13 . ?
Cl2 Rb1 Cl2 90.11(2) 18_556 20_656 ?
Cl2 Rb1 Cl2 148.348(13) . 20_656 ?
Cl1 Rb1 Cl2 133.011(15) 13 20_656 ?
Cl1 Rb1 Cl2 72.666(12) . 20_656 ?
Cl2 Rb1 Cl2 90.11(2) 18_556 19_466 ?
Cl2 Rb1 Cl2 148.348(13) . 19_466 ?
Cl1 Rb1 Cl2 72.666(12) 13 19_466 ?
Cl1 Rb1 Cl2 133.011(15) . 19_466 ?
Cl2 Rb1 Cl2 62.60(3) 20_656 19_466 ?
Cl2 Rb1 Cl2 148.348(13) 18_556 4_465 ?
Cl2 Rb1 Cl2 90.11(2) . 4_465 ?
Cl1 Rb1 Cl2 72.666(12) 13 4_465 ?
Cl1 Rb1 Cl2 133.011(15) . 4_465 ?
Cl2 Rb1 Cl2 109.34(2) 20_656 4_465 ?
Cl2 Rb1 Cl2 77.96(3) 19_466 4_465 ?
Cl2 Rb1 Cl2 148.348(13) 18_556 3_655 ?
Cl2 Rb1 Cl2 90.11(2) . 3_655 ?
Cl1 Rb1 Cl2 133.011(15) 13 3_655 ?
Cl1 Rb1 Cl2 72.666(12) . 3_655 ?
Cl2 Rb1 Cl2 77.96(3) 20_656 3_655 ?
Cl2 Rb1 Cl2 109.34(2) 19_466 3_655 ?
Cl2 Rb1 Cl2 62.60(3) 4_465 3_655 ?
Cl2 Rb1 Rb1 137.542(18) 18_556 17_566 ?
Cl2 Rb1 Rb1 137.542(18) . 17_566 ?
Cl1 Rb1 Rb1 109.402(7) 13 17_566 ?
Cl1 Rb1 Rb1 109.402(7) . 17_566 ?
Cl2 Rb1 Rb1 54.672(11) 20_656 17_566 ?
Cl2 Rb1 Rb1 54.672(11) 19_466 17_566 ?
Cl2 Rb1 Rb1 54.672(11) 4_465 17_566 ?
Cl2 Rb1 Rb1 54.672(11) 3_655 17_566 ?
Cl2 Rb1 Co1 76.863(17) 18_556 9_444 ?
Cl2 Rb1 Co1 161.78(2) . 9_444 ?
Cl1 Rb1 Co1 99.362(2) 13 9_444 ?
Cl1 Rb1 Co1 99.362(2) . 9_444 ?
Cl2 Rb1 Co1 33.734(15) 20_656 9_444 ?
Cl2 Rb1 Co1 33.734(15) 19_466 9_444 ?
Cl2 Rb1 Co1 105.383(15) 4_465 9_444 ?
Cl2 Rb1 Co1 105.383(15) 3_655 9_444 ?
Rb1 Rb1 Co1 60.679(5) 17_566 9_444 ?
Cl2 Rb1 Co1 161.78(2) 18_556 25_566 ?
Cl2 Rb1 Co1 76.863(17) . 25_566 ?
Cl1 Rb1 Co1 99.362(2) 13 25_566 ?
Cl1 Rb1 Co1 99.362(2) . 25_566 ?
Cl2 Rb1 Co1 105.383(15) 20_656 25_566 ?
Cl2 Rb1 Co1 105.383(15) 19_466 25_566 ?
Cl2 Rb1 Co1 33.734(15) 4_465 25_566 ?
Cl2 Rb1 Co1 33.734(15) 3_655 25_566 ?
Rb1 Rb1 Co1 60.679(5) 17_566 25_566 ?
Co1 Rb1 Co1 121.359(11) 9_444 25_566 ?
Cl2 Rb1 Rb1 48.290(16) 18_556 3_665 ?
Cl2 Rb1 Rb1 48.290(16) . 3_665 ?
Cl1 Rb1 Rb1 45 13 3_665 ?
Cl1 Rb1 Rb1 96.196(14) . 3_665 ?
Cl2 Rb1 Rb1 138.243(13) 20_656 3_665 ?
Cl2 Rb1 Rb1 107.280(10) 19_466 3_665 ?
Cl2 Rb1 Rb1 107.280(10) 4_465 3_665 ?
Cl2 Rb1 Rb1 138.243(14) 3_655 3_665 ?
Rb1 Rb1 Rb1 154.402(7) 17_566 3_665 ?
Co1 Rb1 Rb1 116.208(3) 9_444 3_665 ?
Co1 Rb1 Rb1 116.208(3) 25_566 3_665 ?
Cl1 Rb2 Cl1 180 5_656 . ?
Cl1 Rb2 Cl2 112.490(14) 5_656 . ?
Cl1 Rb2 Cl2 67.510(14) . . ?
Cl1 Rb2 Cl2 67.510(14) 5_656 28_656 ?
Cl1 Rb2 Cl2 112.490(14) . 28_656 ?
Cl2 Rb2 Cl2 62.54(3) . 28_656 ?
Cl1 Rb2 Cl2 112.490(14) 5_656 3_655 ?
Cl1 Rb2 Cl2 67.510(14) . 3_655 ?
Cl2 Rb2 Cl2 81.586(10) . 3_655 ?
Cl2 Rb2 Cl2 138.25(3) 28_656 3_655 ?
Cl1 Rb2 Cl2 67.510(14) 5_656 26_546 ?
Cl1 Rb2 Cl2 112.490(14) . 26_546 ?
Cl2 Rb2 Cl2 138.25(3) . 26_546 ?
Cl2 Rb2 Cl2 81.586(10) 28_656 26_546 ?
Cl2 Rb2 Cl2 138.92(3) 3_655 26_546 ?
Cl1 Rb2 Cl2 112.490(14) 5_656 2_665 ?
Cl1 Rb2 Cl2 67.510(14) . 2_665 ?
Cl2 Rb2 Cl2 135.02(3) . 2_665 ?
Cl2 Rb2 Cl2 138.92(3) 28_656 2_665 ?
Cl2 Rb2 Cl2 81.586(10) 3_655 2_665 ?
Cl2 Rb2 Cl2 63.04(3) 26_546 2_665 ?
Cl1 Rb2 Cl2 112.490(14) 5_656 4_565 ?
Cl1 Rb2 Cl2 67.510(14) . 4_565 ?
Cl2 Rb2 Cl2 81.586(10) . 4_565 ?
Cl2 Rb2 Cl2 63.04(3) 28_656 4_565 ?
Cl2 Rb2 Cl2 135.02(3) 3_655 4_565 ?
Cl2 Rb2 Cl2 62.54(3) 26_546 4_565 ?
Cl2 Rb2 Cl2 81.586(10) 2_665 4_565 ?
Cl1 Rb2 Cl2 67.510(14) 5_656 27_456 ?
Cl1 Rb2 Cl2 112.490(14) . 27_456 ?
Cl2 Rb2 Cl2 138.92(3) . 27_456 ?
Cl2 Rb2 Cl2 135.02(3) 28_656 27_456 ?
Cl2 Rb2 Cl2 63.04(3) 3_655 27_456 ?
Cl2 Rb2 Cl2 81.586(10) 26_546 27_456 ?
Cl2 Rb2 Cl2 62.54(3) 2_665 27_456 ?
Cl2 Rb2 Cl2 138.25(3) 4_565 27_456 ?
Cl1 Rb2 Cl2 67.510(14) 5_656 25_566 ?
Cl1 Rb2 Cl2 112.490(14) . 25_566 ?
Cl2 Rb2 Cl2 63.04(3) . 25_566 ?
Cl2 Rb2 Cl2 81.586(10) 28_656 25_566 ?
Cl2 Rb2 Cl2 62.54(3) 3_655 25_566 ?
Cl2 Rb2 Cl2 135.02(3) 26_546 25_566 ?
Cl2 Rb2 Cl2 138.25(3) 2_665 25_566 ?
Cl2 Rb2 Cl2 138.92(3) 4_565 25_566 ?
Cl2 Rb2 Cl2 81.586(10) 27_456 25_566 ?
Cl1 Rb2 Rb1 137.411(2) 5_656 . ?
Cl1 Rb2 Rb1 42.589(2) . . ?
Cl2 Rb2 Rb1 41.784(14) . . ?
Cl2 Rb2 Rb1 104.231(14) 28_656 . ?
Cl2 Rb2 Rb1 45.517(14) 3_655 . ?
Cl2 Rb2 Rb1 154.940(14) 26_546 . ?
Cl2 Rb2 Rb1 100.511(14) 2_665 . ?
Cl2 Rb2 Rb1 97.901(15) 4_565 . ?
Cl2 Rb2 Rb1 108.507(14) 27_456 . ?
Cl2 Rb2 Rb1 69.963(14) 25_566 . ?
Cl1 Rb2 Rb1 42.589(2) 5_656 11_655 ?
Cl1 Rb2 Rb1 137.411(2) . 11_655 ?
Cl2 Rb2 Rb1 104.231(14) . 11_655 ?
Cl2 Rb2 Rb1 41.784(14) 28_656 11_655 ?
Cl2 Rb2 Rb1 154.940(14) 3_655 11_655 ?
Cl2 Rb2 Rb1 45.516(14) 26_546 11_655 ?
Cl2 Rb2 Rb1 108.506(14) 2_665 11_655 ?
Cl2 Rb2 Rb1 69.963(14) 4_565 11_655 ?
Cl2 Rb2 Rb1 100.511(14) 27_456 11_655 ?
Cl2 Rb2 Rb1 97.901(15) 25_566 11_655 ?
Rb1 Rb2 Rb1 145.998(8) . 11_655 ?
Cl2 Co1 Cl2 111.89(3) . 28_656 ?
Cl2 Co1 Cl2 111.89(3) . 27_466 ?
Cl2 Co1 Cl2 104.74(5) 28_656 27_466 ?
Cl2 Co1 Cl2 104.74(5) . 2_675 ?
Cl2 Co1 Cl2 111.89(3) 28_656 2_675 ?
Cl2 Co1 Cl2 111.89(3) 27_466 2_675 ?
Cl2 Co1 Rb1 156.95(3) . 9 ?
Cl2 Co1 Rb1 57.84(2) 28_656 9 ?
Cl2 Co1 Rb1 57.84(2) 27_466 9 ?
Cl2 Co1 Rb1 98.31(3) 2_675 9 ?
Cl2 Co1 Rb1 57.84(2) . 19_566 ?
Cl2 Co1 Rb1 98.31(3) 28_656 19_566 ?
Cl2 Co1 Rb1 156.95(3) 27_466 19_566 ?
Cl2 Co1 Rb1 57.84(2) 2_675 19_566 ?
Rb1 Co1 Rb1 139.482(7) 9 19_566 ?
Cl2 Co1 Rb1 57.84(2) . 3_665 ?
Cl2 Co1 Rb1 156.95(3) 28_656 3_665 ?
Cl2 Co1 Rb1 98.31(3) 27_466 3_665 ?
Cl2 Co1 Rb1 57.84(2) 2_675 3_665 ?
Rb1 Co1 Rb1 139.482(7) 9 3_665 ?
Rb1 Co1 Rb1 58.641(11) 19_566 3_665 ?
Cl2 Co1 Rb1 98.31(3) . 25_566 ?
Cl2 Co1 Rb1 57.84(2) 28_656 25_566 ?
Cl2 Co1 Rb1 57.84(2) 27_466 25_566 ?
Cl2 Co1 Rb1 156.95(3) 2_675 25_566 ?
Rb1 Co1 Rb1 58.641(11) 9 25_566 ?
Rb1 Co1 Rb1 139.482(7) 19_566 25_566 ?
Rb1 Co1 Rb1 139.482(7) 3_665 25_566 ?
Rb1 Cl1 Rb1 89.9990(10) . 19_566 ?
Rb1 Cl1 Rb1 90 . 3_655 ?
Rb1 Cl1 Rb1 180 19_566 3_655 ?
Rb1 Cl1 Rb1 180 . 17_666 ?
Rb1 Cl1 Rb1 90 19_566 17_666 ?
Rb1 Cl1 Rb1 90 3_655 17_666 ?
Rb1 Cl1 Rb2 90 . 17_666 ?
Rb1 Cl1 Rb2 90 19_566 17_666 ?
Rb1 Cl1 Rb2 90 3_655 17_666 ?
Rb1 Cl1 Rb2 90 17_666 17_666 ?
Rb1 Cl1 Rb2 90 . . ?
Rb1 Cl1 Rb2 90 19_566 . ?
Rb1 Cl1 Rb2 90 3_655 . ?
Rb1 Cl1 Rb2 90 17_666 . ?
Rb2 Cl1 Rb2 180 17_666 . ?
Co1 Cl2 Rb1 175.17(4) . . ?
Co1 Cl2 Rb1 88.43(2) . 19_566 ?
Rb1 Cl2 Rb1 87.63(2) . 19_566 ?
Co1 Cl2 Rb1 88.43(2) . 3_665 ?
Rb1 Cl2 Rb1 87.63(2) . 3_665 ?
Rb1 Cl2 Rb1 70.66(2) 19_566 3_665 ?
Co1 Cl2 Rb2 92.79(2) . 25_566 ?
Rb1 Cl2 Rb2 89.733(16) . 25_566 ?
Rb1 Cl2 Rb2 156.74(2) 19_566 25_566 ?
Rb1 Cl2 Rb2 86.146(7) 3_665 25_566 ?
Co1 Cl2 Rb2 92.79(2) . . ?
Rb1 Cl2 Rb2 89.733(16) . . ?
Rb1 Cl2 Rb2 86.146(7) 19_566 . ?
Rb1 Cl2 Rb2 156.74(2) 3_665 . ?
Rb2 Cl2 Rb2 116.96(3) 25_566 . ?


# END of CIF
